(A) The surface water quality criteria for the protection of aquatic life for specific substances are as follows:
Table 8-1 |
Surface Water Quality Criteria for Protection of Aquatic Life |
| CAS Number |
Substances |
Criterion Maximum Concentration (CMC) (Maximum) ((µg/I))[1] |
CMC Conversion Factors (CF) |
Criterion Continuous Concentration (CCC) (4-Day Average) ((µg/I))[1] |
CCC Conversion Factors (CF) |
| Metals (dissolved)[2][3] |
| 7440382 |
Arsenic |
WER(340)(CF) |
1.000 |
WER(150)(CF) |
1.000 |
| 7440439 |
Cadmium |
WER (e(0.9789 [lnH] - 3.866))(CF) |
1.136672 - [lnH] 0.041838 |
WER (e(0.7977[lnH] - 3.909))(CF) |
1.101672 - [ln H]0.041838 |
| 7440473 |
Chromium (III) |
WER (e(0.819 [lnH] + 3.7256))(CF) |
0.316 |
WER (e(0.819 [lnH] + 0.6848))(CF) |
0.860 |
| 7440473 |
Chromium (VI) |
WER(16)(CF) |
0.982 |
WER(11)(CF) |
0.962 |
| 7440508 |
Copper |
WER (e(0.9422[lnH] - 1.700))(CF) |
0.960 |
WER (e(0.8545[lnH] - 1.702))(CF) |
0.960 |
| 7439921 |
Lead |
WER (e(1.273[lnH] - 1.460))(CF) |
1.46203 -[lnH]0.145712 |
WER (e(1.273[lnH] - 4.705))(CF) |
1.46203 -[lnH]0.145712 |
| 7439976 |
Mercury |
WER(1.694)(CF) |
0.85 |
WER(0.9081)(CF) |
0.85 |
| 7440020 |
Nickel |
WER (e(0.846 [lnH] + 2.255))(CF) |
0.998 |
WER (e(0.846 [lnH] + 0.0584))(CF) |
0.997 |
| 7440666 |
Zinc |
WER (e(0.8473 [lnH] + 0.884))(CF) |
0.978 |
WER (e(0.8473 [lnH] + 0.884))(CF) |
0.986 |
| Organics (Total) |
| 60571 |
Dieldrin |
0.24 |
NA |
0.056 |
NA |
| 72208 |
Endrin |
0.086 |
NA |
0.036 |
NA |
| 56382 |
Parathion |
0.065 |
NA |
0.013 |
NA |
| 87865 |
Pentachlorophenol[4] |
(1.005[pH] - 4.869) |
NA |
e(1.005[pH] - 5.134) |
NA |
| Other Substances |
| Chlorine (total residual) |
19 |
NA |
11 |
NA |
| Chlorine (intermittent, total residual)[5] |
200 |
NA |
NA |
| 57125 |
Cyanide (free) |
22 |
NA |
5.2 |
NA |
| Selenium CCC are specified in clause (B) |
| Chloride CMC and CCC are specified in subdivision (5)[1] |
[1]Aquatic organisms should not be affected unacceptably if the four (4) day average concentration specified in this table for a substance does not exceed the CCC more than once every three (3) years on the average and if the one (1) hour average concentration does not exceed the CMC more than once every three (3) years on the average, except possibly where a commercially or recreationally important species is very sensitive.
[2]Aquatic life criteria for these metals are expressed as a dissolved concentration and are calculated using the water-effect ratio (WER) and the specified conversion factor (CF). The CMC and CCC for a dissolved metal are calculated by multiplying the WER by the criterion value or formula and then by the appropriate CF. A value of one (1) must be used for the WER unless an alternate value is established under section 16 of this rule. The dissolved CMC and CCC must be rounded to two (2) significant digits, except when the criteria are used as intermediate values in a calculation, such as in the calculation of water quality-based effluent limitations (WQBELs).
[3]The hardness values used in the equations for these criteria must not be greater than 400 mg/l as calcium carbonate (CaCO3), and the criteria at a hardness of 400 mg/l as CaCO3 are used for a water hardness above 400 mg/l as CaCO3. The term "lnH" is the natural log of hardness.
[4]A CMC and CCC calculated for pentachlorophenol using the equation in this table must be rounded to two (2) significant digits, except when the criteria are used as intermediate values in a calculation, such as in the calculation of WQBELs.
[5] To be considered an intermittent discharge, total residual chlorine must not be detected in the discharge for a period of more than forty (40) minutes in duration, and these time periods must be separated by at least five (5) hours.
(B) The surface water quality criterion for the protection of aquatic life for selenium is as follows:
Table 8-1a |
Surface Water Quality Aquatic Life Criterion for Selenium (CAS # 7782492) |
Criterion Continuous Concentration (CCC) |
| Media Type |
Fish Tissue[1] |
Water Column[5][7] |
| Criterion Element |
Egg/Ovary[2] |
Fish Whole-Body or Muscle[3] |
Monthly Average Exposure |
Intermittent Exposure[6] |
| Magnitude |
15.1 mg/kg dw |
8.5 mg/kg dw whole-body or 11.3 mg/kg dw muscle (skinless, boneless filet) |
1.5 (µg/I) in lentic aquatic systems 3.1 (µg/I) in lotic aquatic systems |
lmage lmage |
| Duration |
Instantaneous measurement[4] |
Instantaneous measurement[4] |
Thirty (30) days |
Number of days per month with an elevated concentration |
| Frequency |
Not to be exceeded |
Not to be exceeded |
Not more than once in three (3) years on average |
Not more than once in three (3) years on average |
[1]Fish tissue elements are expressed as steady-state; the aquatic system should not be experiencing new or increasing inputs of selenium.
[2]Egg or ovary supersedes any whole-body, muscle, or water column element when fish egg or ovary concentrations are measured. Any proposal to sample egg or ovary fish tissue must be submitted to the department for review and approval prior to initiation of sampling, and the department will evaluate all representative egg or ovary fish tissue data to determine compliance with this criterion element.
[3]Fish whole-body or muscle tissue supersedes the water column element when both fish tissue and water concentrations are measured. Any proposal to sample fish whole-body or muscle tissue must be submitted to the department for review and approval prior to initiation of sampling, and the department will evaluate all representative fish whole-body or muscle tissue data to determine compliance with this criterion element.
[4]Fish tissue data provide instantaneous point measurements that reflect integrative accumulation of selenium over time and space in fish populations at a given site.
[5]Water column values are the applicable criterion element in the absence of steady-state condition fish tissue data and for fishless waters. Water column values are based on dissolved total selenium in water and are derived from fish tissue values via bioaccumulation modeling. Instead of the requirement in 327 IAC 5-2-11.4(b)(3)(A)(i)(CC), the thirty (30) day, ten (10) year stream design flow (Q30,10) must be used for deriving total maximum daily loads (TMDLs), waste load allocations (WLAs) in the absence of TMDLs, and preliminary WLAs for tributaries of the Great Lakes system that exhibit appreciable flows relative to their volumes for the CCC water column criterion element applicable to lotic aquatic systems unless data exist to demonstrate that an alternate stream design flow is appropriate for stream-specific and pollutant-specific conditions.
[6]Intermittent Exposure Equation variables mean the following:
WQCint is the water column intermittent element.
WQC30-day is the water column monthly element for either lentic or lotic waters.
Cbkgrnd is the average background selenium concentration.
fint is the fraction of any 30-day period during which elevated selenium concentrations occur, with fint assigned a value $0.033 (corresponding to one (1) day).
[7]The water column criterion element may be modified on a site-specific basis in accordance with clause (C).